1972

NOME: MANOEL GABRIEL SIQUEIRA GUERREIRO
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO ALUVIONAR APLICADA À REGIÃO DE DOM BOSCO E MORRO DO BULE - MINAS GERAIS"
RÉSUMÉ:Cette recherche a eu pour objet de déterminer l'efficience de la prospection alluvionnaire systématique dans la recherche des indices minéralisés. Dans ce but a été choisie une région dont la géologie était connue et où l'on savait exister de petites minéralisations.

1973

NOME: LUIZ CARLOS SURCAN DOS SANTOS
ORIENTADOR: ELYSIÁRIO TÁVORA FILHO
TÍTULO: "EVOLUÇÃO GEOQUÍMICA E MINERALOGIA NA FORMAÇÃO DE UM SOLO NIQUELÍFERO"
ABSTRACT: Seletive samples and a latosolic profile on serpentinite at Liberdade (Minas Gerais) has been investigated in order to elucidate the genesis of the secondary minerals and the main element behaviour during tropical weathering. Nickel bearing minerals and related species were identified by mineralogical, optical, chemical, X-ray diffraction and differential thermal analyses. The parent rock is composed basically of serpentine (90 to 95%). Minor amounts of magnetite, chlorite, spinel, talc, pyroxene, amphibole and goethite are also present. The mineral assemblage of the soil consists of goethite, quartz and chalcedony, chlorite, serpentine minerals, vermiculite, kaolinite, gibbsite and magnetite. Minor amounts of talc, montmorillonite, amphibole (cummingtonite and tremolite), spinel, cromite and rutile are also present. Serpentine gradually alters, with the formation of intermediate phases, into goethite, kaolinite, gibbsite and free silica (chalcedony and quartz). The presence of Mg2+ in a basic environment promotes the formation of montmorillonite and chlorite in an amount proportional to the content of Al2O3 in the original solutions. Both minerals are unstable. Magnetite, rutile and chromite which are stable, remains in the profile and are concentrated mechanically. MgO which is removed more easily than silica was lost. Silica is partially removed and partially precipitated as coloidal silica with later recrystallization. Alumina is concentrated in the upper part of the profile. Some is held in the goethite structure and the rest is constituted by kaolinite and gibbsite. Iron shows a large accumulation in the B horizon as goethite at different degrees of crystallization. Titanium in the soil is either associated with goethite or present as free TiO2 in rutile and anatase or again, in minor quantity, in the magnetite structure. Nickel is concentrated in the C2 horizon, just above fresh serpentinite, by two convergent processes: alteration of the parent rock and leaching of unstable minerals "per descensum" in the B horizon. This leaching is aided by the presence of iron hidroxides giving rise to slight acidity of the soil (pH 6,0) inthe B horizon. However, ideal conditions for nickel precipitation are found in the C2 horizon which has a higher pH (6,8). Nickel is always associated with sheet silicates like serpentine, chlorite, montmorillonite and vermiculite. Nickel is in diadocic substitution of magnesium, mainly in clay fraction. There are no significant amounts of nickel associated with goethite of magnetite. The presence of kaolinite and gibbsite in the B horizon indicates a mature soil.

NOME: ANA MARIA NETTO FERREIRA
ORIENTADOR: LUÍS ALFREDO MOUTINHO DA COSTA
TÍTULO: "PETROGRAFIA DA QUADRÍCULA DE CONCEIÇÃO DO RIO VERDE - MINAS GERAIS"
ABSTRACT:

NOME: ALEXANDRE VALE DE FREITAS FERREIRA
ORIENTADOR: LUÍS ALFREDO MOUTINHO DA COSTA
TÍTULO: "GEOLOGIA DA QUADRÍCULA DE CONCEIÇÃO DO RIO VERDE - MINAS GERAIS"
ABSTRACT:

1974

NOME: JOSÉ MOREIRA DE SOUZA
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO COM BATEIA DO DISTRITO DE DOM BOSCO - MINAS GERAIS"
ABSTRACT: This study describes the investigation of the disitribution of heavy index mineral in an area of approximately 60 square kilometers in the regions of Dom Bosco and Morro Gabriel of central Minas Gerais through the technique of mineral tracing by hand panning and sample concentrate identification. Field and laboratory procedures of sampling and preparing eighty-six panned concentrates for identification with the binocular microscope are reviewed. The physical characteristics of twenty-two indicator minerals including romeite and wulfenite, which had never been found previously in the area investigated, are described and isograde maps showing their distribution are presented. Cinnabar and topaz which are more interesting are discussed from the viewpoint of genesis and possible economic importance. From the data obtained the author concludes thta sampling by hand panning is the most satisfactory procedure in exploring for economic minerals over widespread areas.

NOME: CARLINDA CAMPELO FARIAS
ORIENTADOR: JEANNINE ODETTE CASSEDANNE
TÍTULO: "FOSFATOS MINERAIS DO PEGMATITO DA MINA SAPUCAIA, GALILÉIA, MINAS GERAIS"
ABSTRACT: The Sapucaia pegmatite is granitic in composition and yieds a significant production of muscovite and beryl. The phosphate minerals occur either in intimately intergrowth with many other phosphates or with accessory minerals such a spodumene, beryl, turmaline and sulfides. The chemical analysis, the approximate indices of refraction, the specific gravity, differential thermal analysis and X-ray powder data are listed. Eighteen phosphate minerals from the Sapucaia pegmatite are described and three additionals (unidentified) that may be alterarion products of minerals descibed or know only from this locality.

1975

NOME: GLÍCIA SANTOS BORBA
ORIENTADOR: ELYSIÁRIO TÁVORA FILHO
TÍTULO: "ROCHAS VULCÂNICAS DA FAIXA COSTEIRA SUL DE PERNAMBUCO - ASPECTOS PETROGRÁFICOS E GEOQUÍMCOS"
ABSTRACT:

1977

NOME: ESPEDITA GONÇALVES DE TORRE
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO ALUVIONAR NO COMPLEXO ULTRAMÁFICO-ALCALINO DE SERRA EGRA, PATROCÍNIO - MINAS GERAIS"
ABSTRACT: The research aimed at the evaluation of the alluvial prospecting method in a region of carbonatic intrusions. The alkaline-ultramafic Complex of Serra Negra of Tertiary/Cretaceous Age is intrusive in rocks of the Bambui Group. These rocks are in overthrusting contact with the rocks of the Canastra Group. Both sequences belong to the Upper Precambrian. The work was divided in field and lab stages. The field work consisted of a systematic sampling comprising almost all the N rim of the dome where 138 panned concentrates were collected. The lab work consisted of the splitting of the concentrates and identification of their various constituents. As from the obtained data, surfaces of equal abundance were delimited and comments about the provenience, distribution and association of the minerals were done. The influence of the geomorphology on the behaviour and partition of some of these minerals was also evaluated. The results were quite interesting. It was possible to detect almost all the occurrences previously known, permitting also the discovery of other occurrences still not determined, like crandallite, gold, chalcopyrite, malachite, xenotime, monozite, corundum, siderite, andaluzite and kyanite.

1978

NOME: MARIA SUZANA PESSOA DE SOUZA
ORIENTADOR: JEANNINE ODETTE CASSEDANNE
TÍTULO: "ESTUDO COMPARATIVO DE VÁRIOS MÉTODOS RADIOCRISTALOGRÁFICOS APLICADOS A FOSFATOS DE FERRO E MANGANÊS"
BANCA EXAMINADORA: IGNACIO AURELIANO MACHADO BRITO, JACQUES PIERRE CASSEDANNE, AUGUSTO BAPTISTA
DATA DA DEFESA: 14 DE SETEMBRO
NO DO PROCESSO: 25.370/78
ABSTRACT: This research was made aiming at the evaluation of comparatively several radiocrystallography methods under use and precision of data obtained. The X-Ray diffraction methods (Debye-Scherrer, Precession, Rotation, Weissenberg), the fluorescence analysis, the differential thermal analysis and the thermal gravimetric analysis, were applied to two phosphates of iron and manganese, Eosphorite and Hureaulite, found in pegmatites of the Rio Doce valley and of the Rio Jequitinhonha valley, State of Minas Gerais, Brazil. A very through study was made embracing from the unit cell dimensions up to the group of these phosphates, enabling the addition of new radiocrystallography data to the ones existing in the specialized literature.

NOME: ROGER DIAZ TORO
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "MINERALOGIA DOS ALUVIÕES DIAMANTÍFEROS DUMA ÁREA DA QUEBRADA GRANDE AFLUENTE DO RIO GUANIAMO - ESTADO BOLIVAR - VENEZUELA"
ABSTRACT: This work contains the results of alluvial prospection on stratigraphic horizons in the Quebrada Grande creck, which joints the Guaniamo river, and is located in the Cedeño District, State of Bolivar, Venezuela. Alluvial prospection works were made along a 13kilometer belt, 40 to 300 meters wide, located approximately 450km SSE of Caracas, the country capital. The study aim is to get the necessary information which will let us stablish the possible origin of the Guaniamo diamonds. All mineral besides quarz, identifide in alluvial materials as essential, were microcline, epidote, ilmeno-rutile, garnet, diamond, forsterite and also opaque mineral. Absence of both magnesium ilmenite and chromifem diopside let infere that Guaniamo area diamonds have secondary origin and come from Roraima Formation conglomerate. This is also emphasized by low rounding of gravel size material. Due to lack of proper planning of the mining operations themselves, the samples were collected at randon, but equidistances within a same mine were always kept. Geologically the outcrups occur in a series of diabase, anphibolite and gneissic-granite dikes and following the outcome of age determinations by the K/Ar and Rb/Sr (Mendonza, 1972) methods the rocks have been classified Pre-Cambriam (1800-1500 Myrs) overlain discordantly by the Roraima and Cinaruco formations.

1979

NOME: HAMILCAR D'ÁVILA FREIRE DE CARVALHO
ORIENTADOR: JEANNINE ODETTE CASSEDANNE
TÍTULO: "CONTRIBUIÇÃO A ANÁLISE QUÍMICA QUANTITATIVA APLICADA A FOSFATOS NATURAIS DE PEGMATITOS"
BANCA EXAMINADORA: FRANKLIN DOS SANTOS ANTUNES, J. HANS DANIEL SCHORSCHER, JACQUES PIERRE CASSEDANNE
DATA DA DEFESA: 17 DE JULHO
NO DO PROCESSO: 16.399/79

NOME: NAJLA MAROUN ESTRADA
ORIENTADOR: JEANNINE ODETTE CASSEDANNE
TÍTULO: "ESTUDO COMPARATIVO DE MÉTODOS PARA DOSAGEM DE FÓSFORO EM FOSFATOS NATURAIS"
BANCA EXAMINADORA: JACQUES PIERRE CASSEDANNE, HÉLIO MONTEIRO PENHA, FRANKLIN DOS SANTOS ANTUNES
DATA DA DEFESA: 17 DE JULHO
NO DO PROCESSO: 16.400/79

1980

NOME: CACILDA NASCIMENTO DE CARVALHO
ORIENTADOR: J. HANS DANIEL SCHORSCHER
TÍTULO: "HIDROQUÍMICA DO RIO SARAPUÍ - RJ"
BANCA EXAMINADORA: FRANKLIN DOS SANTOS ANTUNES. JEANNINE ODETTE CASSEDANNE, MÁRIO DA SILVA PINTO
DATA DA DEFESA: 12 DE DEZEMBRO
NO DO PROCESSO: 33.292/80
ABSTRACT: Analysis of the complete course of the Rio Sarapuí-RJ, a NW affluent of Copacabana Bay were made anda data are here presented. The analysis were made "in situ", by colorimetry and titration. They indicate Defficiency of Dissolved Oxigen and characterize Chloride, Sulfide, Ammonia, Nitrite, Cyanide, Total Hardness, pH, Total Iron, Chromium VI and Copper, giving nine hundred and eighty data. The atomic absorption spectroscopy analysis of the soluble fraction (0,45m) characterize Magnesium, Calcium, Chromium, Manganese, Iron, Copper, Zinc, Cobalt, Nickel, Cadmium, Mercury and Lead. Sodium and Potassium were analysed by flame photometry. The instrumental analysis totalize one hundred and forty data. The results obtained permit to classify the river into domiciliar, intermediary and industrial zones, according to the emissions that it receives. All the zones are contaminated by chemical species in different concentrations.

NOME: LINDALVA MARIA JOSÉ DOS REIS CÂMARA
ORIENTADOR: JEANNINE ODETTE CASSEDANNE
TÍTULO: "UTILIZAÇÃO DE INDICADORES QUÍMICOS NA ESTRATIGRAFIA DE DEPÓSITOS CONTINENTAIS CENOZÓICOS"
BANCA EXAMINADORA: ELMO DA SILVA AMADOR, FRANKLIN DOS SANTOS ANTUNES, MANLIO SILVESTRE FERNANDES
DATA DA DEFESA: 16 DE DEZEMBRO
NO DO PROCESSO: 34.515/80
ABSTRACT: Research comprises the development of quantitative chemical analises of some meaningful elements such as: Sodium, Potassium, Calcium , Iron, Aluminum and Silica. The applied methods were satisfactory and proposed , throughout their results, a new metodological option toward characterizing and individualization of lithostratigraphics units and its application as a paleoenvironmental indicator. It's a research that comprises analises of sediments of the terciary and pleistoceno from Taubaté , Espírito Santo and Volta Redonda Basins.

1981

NOME: JEANETE ALVES RIBEIRO
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO COM BATEIA NO MACIÇO ALCALINO DE TANGUÁ E ADJACÊNCIAS, MUNICÍPIOS DE ITABORAÍ E RIO BONITO - RJ"
BANCA EXAMINADORA: FERNANDO ROBERTO MENDES PIRES, JOEL GOMES VALENÇA, AUGUSTO BAPTISTA , HÉLIO MONTEIRO PENHA (suplente)
DATA DA DEFESA: 08 DE OUTUBRO
NO DO PROCESSO: 29.537/81
ABSTRACT: The aim of this work was to check panning prospecting method in a Precambrian basement complex area intrued by a sienitic massif partially surrounded by associated intrusives magmatic breccia (Tanguá Massif). In a first field phase, eluvional and/or aluvional samaples were systematically collected according to a 1Km2 grid . These sample were than submitted to a routine laboratory work (heavy liquid and isodynamic sepration, etc). Heavy minerals were determined by optical examination under a binocular microscope and a polarizing microscope, and chemical methods. When necessary X-Ray diffration was used. The results obtained from the work above were plotted in 23 mineral distribution maps and they allowed to examine the source and mineralogical association of each of the these minerals and to establish preliminary hypotheses. In a second field phases, a sampling control was carried out in order to check the previous conclusions. This study permitted us to find the following mineralogical associations: 1 - Magnetite - Titanite - Leucoxene: Related to syenitic rocks; 2 - Zircon - Monasite - Ilmenite: Related to gneisses and migmatites; 3 - Sillimanite - Almandine Garnet: Related to gneissic rocks derived from pelitic sediments; 4 - Epidote - Grossularite - Andradite: Related to calc - silicate rocks; 5 - Kyanite - Andalusite: Related to gneissic rocks. The presence of kyanite would be taken as the indicator of the transition from the metamorphism between the low to the medium pressure types. Finally, the provenance of numerous others minerals some of wich were heretofore unknown in the area, was determined. These however did not show the strong association cited above.

NOME: RONALDO MELLO PEREIRA
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO ALUVIONAR SISTEMÁTICA APLICADA À REGIÃO DE DIVINO DAS LARANJEIRAS - MG"
BANCA EXAMINADORA: HÉLIO MONTEIRO PENHA, FERNANDO ROBERTO MENDES PIRES. AUGUSTO BAPTISTA
DATA DA DEFESA: 01 DE DEZEMBRO
NO DO PROCESSO: 40.395/81
ABSTRACT: This research aimed to evaluate the method of systematic alluvium prospecting applied to pegmatitic areas. An area of 350 square kilometers approximately, in the central part of the Eastern Brazil Pegmatitic Province was selected; for the studies, and the town of Divino de Lanranjeiras, MG was selected as a field base. Geologically the terrain is covered by the Formação São Tomé, Rio Doce Group, which contains intrusive granitoid rocks, like the Galilea Tonalite and the Palmital Granodiorito, all Precambrian in age. The research was developed into two phases: - fiedl work where all creeks were systematically sampled; when never possible a minimum of 1000 meters spacing between sampling sites was kept. A total of 82 samples were collected. - a laboratory study, where the samples were physically splitted and sirved; factor fracting coas made using heavy liquits and eletromagnetic methods, followed by mineral identification. 36 minerals were described and 17 maps showing the mineral distribution were prepared. Whenever possible provenance and mineral associations were commented. The research presented results, detecting most the previously known occurrences like cassiterite, columbite-tentalite, spodumene, ambligonite, monazite, etc. and also detecting two minerals not yet described (scheelite and anatase) as well as some labile minerals like "gumite" and Fe-Mn phosphate. Some considerations about the sampling and the role of the alluvium were made.

1982

NOME: MARIA DO CARMO BUSTAMANTE JUNHO
ORIENTADOR: HÉLIO MONTEIRO PENHA
TÍTULO: "GEOLOGIA, PETROLOGIA E GEOQUÍMICA PRELIMINAR DO GRANITO TERESÓPOLIS, RJ"
BANCA EXAMINADORA: JOEL GOMES VALENÇA, FERNANDO ROBERTO MENDES PIRES, J. HANS DANIEL SCHORSCHER, RITA ALVES BARBOSA, RUDOLPH ALLARD JOHANNES TROUW (suplente)
DATA DA DEFESA: 17 DE JUNHO
NO DO PROCESSO: 3.260/82
ABSTRACT: The mapping here presented was held in a pre-Cambrian area comprising migmatitic gneises, cut by orthogneisses and post-tectonic granites, as well as basaltic dykes of mesozoic age. The migmatitic gneisses are related to the Santo Aleixo Unit (Penha et alii, 1979). They are acid gneisses with an amphibolitic-tonalitic melanosome and a granitic leucosome. The main structures present are of the stromatic type with minor structures such as nebulitic, agmatic and porfiroblastic types. This unit is cut by orthogneisses of the Serra dos Órgãos Batholith, (Grossi Sad et alii, 1980), represented by a (gr)-(hn)-bi gneissic granite and by a gneissic leucogranite, which portrays an early phase from this magmatism. In the area of the Batholith itself there are some other kinds of intrusive rocks of a latter age and unknown origin. The migmatitic gneisses and orthogneisses show two phases of deformation with NS (Fn-1) and NE-SW (fn) as the main directions. Their mineralogical assemblages are from the high grade amphibolitic facies, superposed by medium grade greenschist facies. An acid to intermediate post-tectonic magmatism cut the gneisses into tabular shaped bodies of various thickness distributed along a NE-SW regional trend. The larger bodies show mainly subhorizontal dips and are sectioned by high angles faults related to a rigid post-Cambrian tectonism. The main fault directions are also coincident with those directions of Fn and Fn-1. We conclude that these granites are allochthonous and post-tectonic. They are (hn)-bi monzogranites with allanite and sphene, and show granodiorite and monzodiorite differentiates. They are referred to this paper as the Teresópolis Granite. In the south of the studied area the granites are gray colored, medium grained, with porphyritic texture. The granites in the north are also gray, but fine-grained, with flow structures and abundant "basic inclusions". These fine-grained granites form also narrow dykes that cut the medium grained granite and the gneisses. They are cut by pegmatites and by dykes of a pink leucogranite, which is the last intrusive phase of this magmatism. The inclusions show the same mineralogy as that of the granites and are of two different types. The "surmicaceous" type is composed basically of mafic minerals and the "microgranular" type is composed of andesite to quartzo-andesite igneous rock, with igenous textures. They most probably are autoliths or restites. The chemical analyses of these granites indicate a magma of trondhjemitic (soda rapakivitic) composition, with a relative potassium enrichment. The pattern of magmatic evolution suggests a trend calc-alkaline. Correlations and comparisons between the Teresópolis Granite and the Andorinha (Penha et alii, 1979a), (Zorita, 1978), Ipiranga (Puget, 1979), Nova Friburgo e Sana (Grossi Sad et alii, 1978 e 1981) granites reveal structural, petrographic and geochemical similarities. These features show that the Teresópolis Granite and the other granites above have some aftinities with granites of the I-type (Pitcher, in Atherton e Tarney, 1979) derived by anatexis from basic continental crust.

1983

NOME: PAULO ROBERTO OLIVA
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO COM BATEIA NA REGIÃO PEGMATÍTICA DA GOLCONDA - MUNICÍPIO DE GOVERNADOR VALADARES - MINAS GERAIS"
BANCA EXAMINADORA: FERNANDO ROBERTO MENDES PIRES, HÉLIO MONTEIRO PENHA, AUGUSTO BAPTISTA
DATA DA DEFESA: 29 DE ABRIL
NO DO PROCESSO: 13.354/83
ABSTRACT: An alluvial exploration with panning was carried out in a area of approximately 140Km2 , located 20Km NW of the Governador Valadares city in the State of Minas Gerais. Geologically the terrain consists of Precambrian biotite gneiss at times cataclastic with layers of amphibolite and pegmatites. The sampling programme involved the sampling of 135 active stream samples in a grid approximately 1km2 in the Onça and São Domingos rivers and their respective tributaries. Thirty-eight minerals were described. Dravite was found in this area for the first time. Trough this research, it was possible to distinguish the following mineralogical assemblages: 1) biotite, garnet, sillimanite and zircon characterize the gneiss. 2) amphiboles, epidote, dravite and pyrite relate with the amphibolites. 3) ambligonite, autunite, beryl, cassiterite, columbite-tantalite, spinel, espodumere, lepidolite, microlite, topaz, tourmalines characterize the pegmatites. In the Onça river beryl loses approximately 75% of its size along the distance of 12km, while in the São Domingos river cassiterite and columbite-tantalite show a size reduction of about 80% and 60% in 7km and 3km respectively. The minerals carried along the Onça river to the Doce river include amphiboles, dravite, garnet, ilmenite, limonite, magnetite, malacon, monazite, muscovite, quartz, rutile, sillimanite, tourmalines and zircon.

NOME: JOSÉ LUIZ PEIXOTO NEVES
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO ALUVIONAR NA REGIÃO PEGMATÍTICA DE GALILÉIA - MINAS GERAIS"
BANCA EXAMINADORA: FERNANDO ROBERTO MENDES PIRES, HÉLIO MONTEIRO PENHA, AUGUSTO BAPTISTA
DATA DA DEFESA: 13 DE DEZEMBRO
NO DO PROCESSO: 008572/83-9
RÉSUMÉ: Cette recherche a eu pour but de dester la méthode de prospection alluvionnaire dans la région pegmatitique de Galiléia (MG). Les pegmatites de cette région sont encaissées dans les micashistes de la Formation são Tomé, dans la Tonalite Galiléia, dans la Granodiorite Palmital et dans le Granite Urucum, tous datés du Précambrien. Le travail a été divisé en deux étapes: 1) Travail de terrain - Il a consisté dans un échantillonnage systématique suivant une maille de 1km. 87échantillons ont été collectés dans les thalwegs et concentrés à la batée. 2) Travail de laboratoire - Il a consisté dans la séparation des concentrés et l'identification de leurs constituants. 28 minéraux on été d`terminés et décrits. A partir des résultats obtenus des cartes de distribution ont été réalisées. Le comportement des minéraux, leurs associations et leur provenance ont été discutés. Les résultats obtenus sont trés satisfaisants: les indices déjá connus en place ont été retrouvés en alluvions (spoduméne, chalcopyrite, cassitérite) et de nouveaux ont été découverts (scheelite, anatase, or, chrysobéryl) qui démontrent l'efficience de la méthode.

1985

NOME: EDUARDO GOMES DOS SANTOS
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "MINERALOGIA E ZONEOGRAFIA DO CAMPO PEGMATÍTICO DA GOLCONDA - MUNICÍPIO DE GOVERNADOR VALADARES - MG"
BANCA EXAMINADORA: AUGUSTO BAPTISTA, FERNANDO ROBERTO MENDES PIRES, HÉLIO MONTEIRO PENHA
DATA DA DEFESA: 13 DE AGOSTO
NO DO PROCESSO: 017398/85-96
ABSTRACT: The pegmatites of the Golconda Region occur preferentially embedded in the biotite and cataclastic gnaisses inserted with beds of amphibolites Precambrian in age related to the Paraíba do Sul Group. Two very distinct types occur. One characterized by simple mineralogy and structure, and the other, by complex mineralogy and zoned structure. Pegmatites of the first type occur in geomorphologic marsh unit and those of the second type occur predominantly in the hills (Serra dos Ferreiras) and, when they do not appear zoned, they show themselves albitized to divide the area into two different domains. The description of identified minerals and data about the orientation of pegmatties, forms, sizes and relation with the wall rock, are presented in the text and are included in the index cards of the individual description of the pegmatites that constitue the attachment. It must be noted that the principal mining activity of the area is primitive mining for columbite-tantalite and gems. Many are the remaning mining sites from the 40's and 50's presently abandoned and/or completely caved in, obstructing the direct access for study of its mineralogy, which obliged the use of panning for concentration of the wastes and posterior processing in laborators. The pegmatites product feldspar, mica, beryl, columbite, tantalite and gems.

NOME: MARÍLIA INÊS MENDES BARBOSA
ORIENTADOR: FERNANDO ROBERTO MENDES PIRES
TÍTULO: "GEOQUÍMICA DAS FAIXAS MÁFICAS-ULTRAMÁFICAS, PLUTONITOS E MIGMATITOS DO GREENSTONE BELT BARBACENA, NA REGIÃO DE CONSELHEIRO LAFAIETE (MG)"
BANCA EXAMINADORA: JOEL GOMES VALENÇA, RUDOLPH ALLARD JOHANNES TROUW, EDUARDO ANTONIO LADEIRA
DATA DA DEFESA: 30 DE SETEMBRO
NO DO PROCESSO: 021661/85-23
ABSTRACT: The geology of the manganiferous district of Conselheiro Lafaiete, at the southern portion of the Minas Gerais State, represents a fraction of typical granite-greenstone province. Precambrian metamorphic rocks of different ages which outcrop in the region, have an apparent basement composed of migmatitic-gneissic complex of the Mantiqueira Group. Barbacena Group Barbacena Group comprises a volcanicplutonic assemblage similar to those classified as Greenstone Belt. The lowermost unit of the Barbacena Group is constituted by ultramafic rocks, talc chorite schists at present, compositionnally similar to the basaltic komatiites of several archean Greenstone Belts, and equivalent to phanerozoic periodites. They are marked by high-Mgo content (> 19%), low values for alkalis (mainly K20 <0,1%), relative enrichment in Cr and Ni, and odd ratios CaO/A12O3 (@ 1), although sometimes this ratio been affected by seletive decalcificationj and a slight enrichment in aluminium. The rocks have similar geochemical trend to the ocean floor basalts (OFB). The mafic rocks of the Barbacena Group, represented by amphibolites and amphibole shists, correspond to the middle stratigraphic unit and spatially widespread. They are correlated in the archean Greenstone Belts to basalts and andesites of the tholeiitic series (TH)

1986

NOME: ARIADNE DO CARMO FONSECA
ORIENTADOR: FERNANDO ROBERTO MENDES PIRES
TÍTULO: "GEOCRONOLOGIA DAS ROCHAS GRANÍTICAS E SUAS ENCAIXANTES NA CIDADE DO RIO DE JANEIRO, RJ"
BANCA EXAMINADORA: JOEL GOMES VALENÇA, UMBERTO CORDANI, RITA ALVES BARBOSA
DATA DA DEFESA: 03 DE MARÇO
NO DO PROCESSO: 2.281/86-16
ABSTRACT: In this work are presented the analytical results obtained by Rb-Sr and K-Ar isotopic and fission-tracks dating methods of some metamorphic and igneous rocks outcroping in the Rio de Janeiro city. The strongly deformed gneissic rocks were generated under conditions of pressure and temperature related to high grade metamorphism. Magmatic rocks of basic and acid compositions, deformed or not, intrude the metamorphic sequence. Dykes of basalt, diabase and alkaline rocks related to Mesozoic tectonism occur elsewhere in the area. The whole rock Rb-Sr isochron age are characteristic of the Brazilian Cycle. The ages between 750 and 550m.y. are related to the tectonic phase, with deformation, metamorphism and anatexis of magmatic precursors and preexistent crustal materials and the intrusion of gabbroic and granodioritic magmas. The intrusion of late and post-tectonic granites occurred between 550 and 450m.y. The comparison between initial ratios and petrographic studies suggests different origins for the metamorphic rocks: either magmatic precursors, which probably generated the gneisses of Inferior Serie and plagioclase-gneisses, or preexistent materials, which may have generated leptinites and biotite gneisses. However the elevate initial ratios don't determine if the leptinites and biotite-gneisses were formed by the metamorphism and anatexis of brazilian sediments or rejuvenesce of the older metamorphic crustal rocks. The K-Ar age of 476m.a. in hornblende, of anfibolite, is related to regional cooling fo the Brazilian Cycle. However the ages of plagioclase of diorites are discordant, either older or younger than other ages. Pission-tracks dating in apatites, of two diorites and one plagioclase-gneiss, produced ages in the interval between 85 and 124m.y. These dates represent the cooling below 110oC (retention temperature of fission tracks in apatite) of the rocks, interpreted as consequence of ascensional movements associated with the continental uplift, resulting of the mantle intumescence, during South Atlantic opening.

NOME: TARCÍSIO PEREIRA DA CUNHA
ORIENTADOR: PÉRSIO DE SOUZA SANTOS
TÍTULO: "DESENVOLVIMENTO DE MÉTODO PARA ESTUDO DOS MINERAIS DOS FOLHELHOS OLEÍGENOS DA FORMAÇÃO IRATI"
BANCA EXAMINADORA: FRANKLIN DOS SANTOS ANTUNES, ELMO DA SILVA AMADOR, IGNACIO AURELIANO MACHADO BRITO
DATA DA DEFESA: 21 DE MAIO
NO DO PROCESSO: 009865/86-95
ABSTRACT: This work is about the mineralogy of Irati Formation shales employed by Petrobrás in the Petrosix Process in São Mateus do Sul (Paraná). The study involved the developement of a method in which cementing agents were "degraded", allowing the separation of individual minerals and their mineralogical classification. The work was carried out through two stages. In the first stage the shales were characterized through chemical and mineralogical analysis, followed by an evaluation of the effect of cementation on Shales minerals. During this stage the most cemented rocks - the oil shales were also determined These results led to the definition of "xisto original de processo" from Petrosix Process as the representative sample of the cemented materials. Eighth cement degradation methods were applied to this representative sample and evaluated through X-Ray difractometry and infrared spectroscopy of the resulting materials. From these results a analysis route was defined and applied throughout this work. The second stage involved the granulometric and mineralogical analysis of the resulting materials, and the results defined the largest particle sice that could be used with the method. The results of mineralogical analysis have also shown that "xisto Original de Processo" consists of quartz, plagioclase, feldspar, mica and the clays kaolim illite and montmorillonite. It was concluded that the main cementing agent consists of organic matter and that the clays are bound to the cementing agent. It was also carried out a quantitative mineralogical analysis through physical, chemical and granulometric methods.

1987

NOME: EURICO ZIMBRES
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO COM BATEIA NO MACIÇO ALCALINO DE CANAÃ E ADJACÊNCIAS, MUNICÍPIO DE DUQUE DE CAXIAS - RJ"
ABSTRACT: In this work was used panning over a Precambrian basement complex area with alkaline rocks (Canaã Massif). In the field phase, alluvional and elluvional samples were systematically collected according to a 500 meters grid. These samples were, then, submited to a routine laboratory work (heavy liquid and isodynamic separation etc.). Heavy minerals were determined by optical examination under a binocular microscope and a polarizing microscope and chemical methods. The results obtained from the work above were ploted on 12 minerals distribution maps which allow to examine the source and mineralogical association of each of these minerals. This study permitted to find the following mineralogical associations: 1. Corundum, spinel and zircon, related to alkaline rocks. 2. Ilmenite, sillimanite, almandine garnet and monazite, related to granitic migmatites. Three blue gem corundum occurrences related to alkalines pegmatites were discovered. Chemical compositions of zircon and titanites were described.

1988

NOME: MARIA ELIZABETH ZUCOLOTTO
ORIENTADOR: CRISTINA MARIA WIEDEMANN
TÍTULO: "METEORITOS METÁLICOS, UMA VISÃO GERAL"
ABSTRACT: A metallographic investigation of macro and microstructure,supported by microprobe and X-ray examination, has been made in five Brazilian iron-meteorites. The Soledade is lightly shocked coarse octahedrite, Og, rich in carbides. Bandwidth 2-4 mm, HV 225 ( 15, Neumann bands, subgrains, rhabdites, cohenite, policrystaline troilite type 3 . Belongs to group IAB, with 6,78% Ni, 98.5 ppm Ga, 420 ppm Ge, and 3.9 ppm Ir. This meteorite was briefly artificially reheated. Pirapora is a shocked an reheated hexahedrite, H, formed by clear and frost atching kamacite, with decorated and fresh Neumann bands, rhabdites (giant, plate, clusters and microrhabdites), chromite and remelted troilite type 5. Belongs to group IIA, with 5.38% Ni, 59.5 ppm Ga, 190 ppm Ge, 28 ppm Ir. Nova Petropolis is a shocked and annealed medium octahedrite, Om, Bandwidth 1.1 ( 0.1 mm, L/W ( 25, HV 170 ( 20. It presents annealed and decorated Neumann bands, rhabdites, schreibersite and recrystalzied troilite type 4. Belongs to group IIIA, with 7.65% Ni, 19.7 ppm Ga, 36.5 ppm Ge and 19.3 ppm Ir. Itutinga is a shock hardened, medium octahedrite, Om. Bandwidth 1.0 ( 0.1 mm, L/W ( 25, structure, presenting hardness range from HV 230 to 340. Neumann bands, subgrains, rhabdites, carlsbergite and twinned troilite type 2. Belongs to group IIIA, with 7.2% Ni, 18.6 ppm Ga, 36 ppm Ge and 13 ppm Ir. Sanclerlândia is a lightly shocked medium octahedrite, Om, Bandwidth 1.0 ( 0.1 mm. It can be found Neumann bands, HV 250 ( 20, subgrains, rhabdites, carlsbergite and lamellar troilite daubreelite of type 1. Group IIIA, with 7.47% Ni, 11.6 ppm Ga, 36.4 ppm Ge and 7.5 ppm Ir. Comparing the meteorites studied with other known brazilian irons, we verify that: the Itutinga, Nova Petrópolis and Soledade are independent irons. On the other hand, Sanclerlândia is closely related with the Veríssimo (Go) iron. However a cross examination should be carried out to determine if these two meteorites are a paired fall. Despite of the fact that Pirapora and Angra dos Reis Iron are chemically and structurally closelly related, there are some minerallogical differences (the presence of cohenite in Angra dos Reis chromite in Pirapora) that put the paired fall hypoteses in question.

NOME: NELSON CESAR CHAVES PINTO FURTADO
ORIENTADOR: CARLTON ANTHONY TAFT
TÍTULO: "SOBRE A IMPORTÂNCIA DO ALKALIDITIOFERRATO, KFeS2, NA GÊNESE DO MINERAL YAVAPAIITA"
ABSTRACT: This work describes the synthesis, experimental methods and accesible theory in order to obtain in laboratory poli and mono crystal synthetic iron sulphide KFeS2 Alkali-Di Thioferrate and subsequent treatment of hidrogenation and oxygenation at high temperatures. It was thus necessary to construct a special furnace with controlled atmosphere and pressure which is shown in details permiting its reproduction. The monoclinic structure of KFeS2 indicated lattice parameters of ao = 7.07Å, bo = 11.36Å, co = 5,41Å, ( = 112.76Å, similar to those found in the ASTM Files. The growth characterization of the mono crystal using the Vertical BRIDGMAN Method is also discussed. The crystals were grown at a velocity of 8 mm/hr (During a total period of 62 hours) indicative a (110) cleavage plane. In this manner was possible to obtain crystals with 40 mm length and 1 cm width. The changes observed in the samples treated under vacuum and hydrogen atmosphere at a temperature of 500o C for a period of 1 hour were similar indicating a new anstable phase coexisting with that of the un-treated sample. In order to measure the quantify of hydrogen absorved a high pressure reactor was used. Details of this experimental procedure are given. The oxidation of KFeS2 was done at temperatures between 350 and 650o C yelding at 400o C the formation of the mineral yavapaiite Kfe (SO4)2.

1990

NOME: RENATA ELIANE FRANK
ORIENTADOR: FERNANDO ROBERTO MENDES PIRES
TÍTULO: "GEOLOGIA, PETROLOGIA E MINERALIZAÇÕES ESTANÍFERAS DO COMPLEXO GRANÍTICO DE SANTA BÁRBARA, RONDÔNIA, BRASIL"
ABSTRACT: The Santa Barbara Granitic Complex is a part of the Rondonian Tin Province. It displays a subrounded shape in surface with a 6 km diameter. It is intrusive in the Xingu Complex gneisses. Contacts with country rock are usually concealed by thick soil cover, but blocks of the Xingu Complex milonitized biotite-rich Augen gneisses in the northeastern boundaries of the Santa Barbara Granitic Complex suggest tectonic contacts. Under the petrographic viewpoint, the Santa Barbara Complex shows distinct primary(magmatic) and secondary(metasomatic) features characterizing two lithologic facies. The primary facies represent about 90% of the total exposed area of the complex and is subdivided into three granitic types: 1) SERRA AZUL GRANITE (Gsa): dominant type, represented by a coarse-grained equant biotite-granite, which usually occurs at the border zone of the complex. 2) SERRA DO CICERO GRANITE (Gsc): marked by the porphyritic texture and by the fact that encircles the Santa Barbara Granite. 3) SANTA BARBARA GRANITE (Gsb): a fine-grained biotite-granite showing close relationships with the mineralization. The granites of the complex exhibit high SiO2 content (73-74%) and Al2O3, K2O, Na2O and CaO contents, which indicate calcalkaline (Wright, 1969) and subaluminous compositions (Shand, 1927). Granites are strongly differentiated. Trace-elements studies demonstrated enrichments in F, Rb, Y, Li, Sn, Nb, Cu, Pb, Zn, Mo, Ce, La and Co, and impoverishment in Ba and Sr. The late and post-magmatic or metasomatic events are monitored by petrographic work and geochemical data. All the granites types show in different proportions, late and post- magmatic and metassomatic transformations (microclinization, albitization, silicification and greisenization). During the greisenization process the topaz was formed at the expenses of the feldspar breakdown. Muscovitization of biotite and feldspars and the cassiterite precipitation, correspond to the principal hydrotermal alterations in the greisens. Tin mineralizations (primary and secondary) are intimately associated with the Santa Barbara Granitic Complex. Primary mineralizations occur either as endogreisen, exogreisen or quartz-veins, controlled by the fracture system oriented following the northeast - southwest direction. These fractures were active during the emplacement of the granites. Secondary tin mineralizations are the product of the intense weathering of the granites which afforded erratic, high grade cassiterite concentrations in the present valleys and palaeovalleys. The positioning of the Santa Barbara Granitic Complex is related to an intracontinental rifting and can be explained by the granite intrusion model controlled by zones of crustal weakness and partial melting, involving the Serra Providencia granite, the probable precursor of the Rondonian Granites.

NOME: JULIO CEZAR MENDES
ORIENTADOR: CRISTINA MARIA WIEDEMANN
TÍTULO: "GEOLOGIA E PETROLOGIA DO COMPLEXO INTRUSIVO DE RIO NOVO DO SUL -ES"
ABSTRACT: This thesis comprises the geological mapping (scale 1:25.000) and interpretation of an area about 80 km2 in the south of the state of Espírito Santo, near the town of Rio Novo do Sul. The area contains several intrusive bodies (The Rio Novo do Sul Intrusive Complex) with rock composition ranging from quartz-diorites to granites (intermediate rocks are quartz-monzodiorites, quartz-monzonites, tonalites and granodiorites), which are enclosed in orthogneisses of Braziliano age and migmatitic banded gneisses (sillimanite-garnet gneisses) of probably Transamazonic age. All these rocks are part of the Alegre Complex, which belongs to the Ribeira Mobile Belt, of Braziliano age. Magnetic data show a strong anomaly in the region, indicating the presence of a large subsurface structure of basic magmatic body. This, combined with the irregular shape of intrusions mapped on the surface could indicate that they represent a set of apophyses and stocks. Dominating among the intrusive rocks are homogeneous granodiorites and quartz-diorites. The other lithologies outcrop only in isolated areas or in mixed zones of rocks. Sometimes, restricted compositional variations may occur. There are well developed flow structures (linear or planar) that tend to be paralell to the schistosity of the enclosed rocks. The degree of deformation of the intrusive is not significant. Homogeneous rocks whithout structural complications are prevailing, and only in some quartz-dioritic portions it is possible to observe turbulent flow structure, small shear zones and/or faulted syn-intrusive veins. The contacts between the enclosing rocks and the several rock units of the complex rarely crop out. In the mixed zones of rocks sharp and irregular veined contacts are found, as well as pillow-like structures. Many granitic dykes and quartz-feldspatic veins cut all the lithologies, showing an irregular strike and shape. Microdiorite dykes of small thickness cut mainly the gneisses, having melted them in some points. The petrographic characteristics of the intrusive rocks are repetitive. They all have a similar mineralogy and predominantly hipidiomorphic granular and porphiritic texture. The dominant potash feldspar is microcline, commonly of microperthitic type. Amphibole of probably iron-hastingsitic composition is well observed in the diorites, and not present in the granites, while in the granodiorites it occurs in trace amounts. In several samples this mineral appears replaced by biotite, and in only on thin section of quartz-diorite it rims augitic pyroxene. Reaction contacts can be found, as examplified by plagioclase corroded by microcline and vice versa, as well as intergrowths between quartz and microcline (graphic intergrowth) and quartz and plagioclase (myrmekite). The plagioclases and biotites determine the primary foliation of the rocks that show flow structure. In microdiorites, the plagioclase can exhibit corroded borders. Apatite and zircon are the accessory minerals most common il all lithologies. The chemistry of the rocks from Rio Novo do Sul Complex reveals a magmatism rich in some elements, such as Fe, K, Ti and P (mainly granodiorites and quartz-diorites) and slightly depleted in Na, in comparison with an average of analyses from the literature. The different lithologies have a peraluminous character (i.e., Al2O3/Na2O + K2O + CaO 1,1), and are oversatured in SiO2, according to their petrographic and normative composition. With regard to the determination of the petrogenetic type of the granitoids, the magnetite-series rocks predominate. The study of several diagrams points to characteristics corresponding to I-type and S-type magmas, as well as to a calc-alkaline/alkali-calcic character of this complex. The whole geochemical data indicate an origin of magmas produced in a transitional environment (end of a compressive cycle/beginning of extensive cycle). Fractional crystallization processes seem to play a major role on the genesis of the intrusive rocks of Rio Novo do Sul. Nevertheless, mechanisms of partial fusion and magma mixing were probably important. The Rio Novo do Sul Intrusive Complex shows similar characteristics to other intrusive complexes from the southern part of Espírito Santo, such as the Castelo and Iconha Intrusions.

1991

NOME: ISABEL PEREIRA LUDKA
ORIENTADOR: CRISTINA MARIA WIEDEMANN
TÍTULO: "GEOLOGIA, PETROLOGIA E GEOQUÍMICA DO COMPLEXO INTRUSIVO JACUTINGA-TORRE, MIMOSO DO SUL, ES"
ABSTRACT: A small portion of the Ribeira Mobile Belt (Brasiliano/Panafrican in age) was studied in detail by focussing the Jacutinga-Torre Intrusive Complex in the neighbourhood of Mimoso do Sul in southern Espírito Santo. Geological mapping (1:25.000) of the intrusive units as well as of their enclosing rocks revealed three individual magmatic bodies: the Torre, the Jacutinga and an orthogneissic unit of regional expression. The Torre unit comprises three roughly concentric domains of melanocratic to leucocratic igneous rocks, grading from diorites to quartzmonzonites, with the predominance of monzodiorites and monzonites. The Jacutinga unit comprises meta-gabroic rocks and is separated from the Torre intrusion by a string of orthogneissic rocks, thant, on the other hand, seem to be intimately related to the meta-gabroic rocks of Jacutiga. The enclosing rocks to this sequence consist of migmatitic banded gneisses associated with sillimanite-quartzites. The schistosity of these banded gneisses is sub-horizontal near the city of Mimoso do Sul, turning to sub-vertical around the contacts of the intrusive Torre structure, where it dips towards its center. A migmatitic ring (granitization ring) grading to a diatexite of leuco-granitic composition characterizes this border region. The Torre intrusive body shows an inversed zoned diapiric structure, with sub-vertical dipping flow structures, grading from a centimeter to a meter scale. Igneous lamination as well as bedding can be clearly observed. The predominant minerals are mesoperthite (K-feldspar and plagioclase An25-35 intergrowth) plagioclases An25-35, microcline, titaniferous biotite, Fe-augite and hypersthene. At the border plagioclase and microcline occur as separated phases. The microcline is only found at the external domain. The clinopyroxenes (calcium-rich Fe-augites) are restricted to the two inner zones. They are replaced by amphibole at the external zone. Orthopyroxene (hypersthene) may be locally found in the internal zone. Geochemical analyses on whole rock samples of the Torre intrusive show high K contents and a very low Rb/Sr ratio, due to the high Sr content. These rocks show calc-alkaline-monzonitic (high K) to alkaline trend. Two genetic hypothesis for the magma generation are discussed: diversification from one parental magma or homogenization of two parental magmas followed by diversification. The age of the massif (490 My., U-Pb in zircon, SOLLNER, pers. com.), associated with the alkaline tendency showing by these rocks, points towards the magmatic-arc maturation, in a distensional tectonic phase. The meta-gabbroic body of Jacutinga comprises gabbro-noritic rocks. The rock composition is variable, grading from very fine grained melanocratic meta-gabbros up to coarse-grained leucocratic meta-gabbros. This suggests an internal structure similar to that of the Torre intrusion. Almost all these Jacutinga rocks show a primary mineral orientation. Despite of these preserved igneous structures, some metamorphic features are observed: hornblende poikiloblasts (evolved from the original minerals), garnet (occurring along fractures) and corona structures (olivine-plagioclase contacts). The metamorphic effects changed the chemistry of these rocks, leading to an open system, with water supply and a probable contamination and mobilization of some elements (Na, K, Rb, Sr). Nevertheless a tholeiitic trend of the original magma can still be recognized.

NOME: PATRÍCIA BARBOSA DE ALBUQUERQUE SGARBI
ORIENTADOR: JOEL GOMES VALENÇA
TÍTULO: "PETROGRAFIA E GEOQUÍMICA DA FORMAÇÃO MATA DA CORDA NA REGIÃO DE CARMO DO PARANAÍBA, MG"
ABSTRACT: This work focuses on relevant geological, mineralogical, petrographic and chemical features of the lavas and subvolcanic rocks of the Mata da Corda formation, as well as on the mode of occurrence and petrographic features of the volcanoclastic and epiclastic rocks of the same formation. The studied area, around 450 km2, is situated near the town of Carmo do Parnaíba (western Minas Gerais state), being part of the Cretaceous Sanfranciscan basin. This basin, represented by the Areado and the Mata da Corda formations, is 500 m thick and unconformably overlies folded metapelites of the Upper Proterozoic Bambuí group. The Areado formation (Lower Cretaceous) consists of fluvial polimitic conglomerates (Abaeté member), lacustrine shales, sandstones, limestones and marls (Quiricó member), and aeolian and fluvio-deltaic sandstones (Três Barras member). The Mata da Corda formation (Upper Cretaceous) overlies the latter formation, separated by local erosive unconformities. It comprises a 40 to 80 m thick pile of K-rich mafic to ultramafic alkaline lavas (Patos facies), volcanic conglomerates and sandstones (Capacete facies) and clayey sandstones with little volcanic contribution (Urucuia facies). The lavas and non-volcanoclastic rocks have a larger spatial distribution and are volumetrically more significant than the volcanoclastic rocks. The lavas form small exposures (frequently, very weathered) of massive thin horizontal and subhorizontal, poorly-vesiculated flows (in places, individually, not exceeding 0,5 m thick). In some outcrops, the extrapolated thickness of a sequence of flows may reach 10 m. According to the IUGS classification (Streckeisen, 1980) the Mata da Corda lavas are ultramafilites, mafitites, leucitites and kalsilitites. These ultramafitites and mafitites have unidentified felsic phase(s) and estimated values (vol. %) of mafic index from 80 to 70 and 60 to 70, respectively; where as the leucitites and kalsilitites contain leucite (pseudomorphs) and kalsilite (pseudomorphs and fresh and clear grains), and get their names from that more abundant felsic phase. All these lavas are all feldspar-free, with plentiful abundant clinopyroxene (mostly, diopside), perowskite and Ti-magnetite, and show very fine to meduim-grained porphyritic to seriated textures. An interstitial material is always present and often intensely altered to zeolites ans clay minerals. In some rocks it has been determined as kalsilite based on electron microprobe analysis; but in other rocks this material could not be accurately identified and it has been modally considered as an unidentified felsic phase. The ultramafitites and mafitites are porphyritic to seriated rocks. The porphyritic types show phenocrysts and microphenocrysts (up to 20 vol. %, and 0,2 to 2.0 mm in size) of olivine (Fo91-84), clinopyroxene (diopside), perowskite, Ti-magnetite, melilite (euhedral and subhedral pseudomorphs), apatite and phlogopite (rarely, as 3.0 mm large plates). The very fine to fine-grained groundmass has clinopyroxene (diopside, up to 40%), Ti-magnetite, perowskite unidentified interstitial material, and may also contain minor amounts of phlogopite and apatite. The seriated types have coarser grains but are modally and mineralogically akin to the previous types. The leucitites and kalsilitites are very similar fine to medium-grained rocks, very frequently with a typical seriated texture. Some of then, however, may develop textures which resemble those of the ultramafitites and mafitites. Mineralogically, the leucitites and kalsilitites are similar to the latter groups of rock, with the exception that they contain leucite (subhedral pseudomorphs) and kalsilite (euhedral pseudomorphs and/or anhedral fresh grains). Both feldspathoids occur as essential phases in the seriated leucitites and kalsilitites or in the very fine-grained intergranular groundmass of the porphyritic leucitites. In these porphyritic rocks, these feldspathoids, in spite of being found in the groundmass, are absent from the phenocrysts and microphenocrysts, which consists of clinopyroxene (diopside to salite), Ti-magnetite, apatite and perowskite. The above mentioned rocks (usually, the fine-grained type) may contain scarce and small (mostly, <20 mm across) cognate inclusions of fine to medium-grained cumulate rocks, consisting of diopside, perowskite, Ti-magnetite, phlogopite and kalsilite. Most commonly, the inclusions are kalsilite pyroxenites, but more rarely, perowskite modally dominates and they become kalsilite "perowskitites". In both cases, kalsilite is an interstitial phase. Thirty one samples of the Mata da Corda lavas have been chemically analysed. These data indicate that the lavas are all ultrabasic. Fourteen of these samples, which showed more important signs of secondary oxidation and other kinds of alteration, were separated. The other representative rocks were subdivided in two groups (GI and GII), according to the K2O/Na2O and K2O values. GI is potassic and has (WT%) SiO2="38-42," TiO2="5-7," Al2O3="5-8," Fe2O3="4-5," FeO="8-9," MgO="8-14," CaO="11-17," K2O="1-3" and Na2O>0-2; whereas GII is ultrapotassic, with (WT%) SiO2=43-45, TiO2=5-8, Al2O3=7-9, Fe2O3=3-4, FeO=7-9, MgO=8-9, CaO=8-12, K2O=4-7 and Na2O>0-2. (2) In the Na2O+K2O versus SiO2 plot, the compositions delineate a trend from moderately (GI) to strongly (GII) alkaline. (3) The compositional spectrum of the lavas shows mainly non-linear variation trends of increasing SiO2, Al2O3, K2O, Na2O, Nb, Zr and Y, and decreasing FeO, CaO, Cr and Co, with decreasing MgO. (4) Discrimination diagrams using SiO2, CaO, MgO, and FeO (total iron) exhibit most lava compositions in fields of kamafugitic affinity.

1992

NOME: FLÁVIO WOLFF
ORIENTADOR: JOEL GOMES VALENÇA
TÍTULO: "CARACTERIZAÇÃO PETROGRÁFICA, LITOGEOQUÍMICA, QUÍMICA MINERAL E GEOTERMOMETRIA DE ROCHAS DE ALTO GRAU METAMÓRFICO DO COMPLEXO ANÁPOLIS-ITAUÇÚ, GOIÁS"
ABSTRACT: The Anapolis-Itauú Complex, in Goias State, Brazil, is part of the Alfenas granulitic belt. The complex is composed mainly of rocks of the amphibolite/granulite facies, showing often, effects of the role played by very intense tectonic processes. This renders difficult the identification of the boudaries between these rocks in terms of their different origins. In this work besides rocks of a lower metamorphic grade, TH1 and TH2 types of ocean tholeiites and an igneous calc-alkaline sequence, both metamorphosed under granulite facies conditions, are also identified. Concerning the sedimentary-derived high-grade rocks, the overall data indicate the presence of granulitic rocks derived from original materials whose compositon approximate those of the pelite-graywacke compositional range. In this context, a thought is advanced that among these granulitic rocks, some may also have originated by recrystallization of leucosomatic material derived by partial melting of these sedimentary components. Observed parageneses and other kinds of evidence suggest that the granulitic rocks formed under two different pressure regimes, of which an earlier low-pressure type was followed by a medium to high-pressure type. At present, the characteristic minerals assemblages assigned to the latter type arc widely dominant in the studied rocks. The geothermometric results indicate that these high-grade mineral assemblages achieved an equilibrium temperature around 800oC (opx-cpx pair). The amphibolite facies rocks predominantly correspond to portions of a TTG terrain involved in the granulitic belt, remmants of overlying supracrustal rocks or to elongated portions of retrogressive granulitic rocks, these widely controled by tectonic dynamics. The lithogeochemistry, attached to the lithological association found in this work points to the possibility that part of studied area corresponds to a granulitized plutonic segment of a root of greenstone belt. With regard to granulitized calc-alkaline sequence mentioned above, it may be interpreted as representing ancient magmatic are rocks associated with a tectonic setting somewhat analogous to a modern orogenic continental margin.

NOME: THAÍS CRISTINA DE MONTE ALVERNE VARGAS
ORIENTADOR: JACQUES PIERRE CASSEDANNE
TÍTULO: "PROSPECÇÃO ALUVIONAR E RECONHECIMENTOS GEOLÓGICO E GEOMORFOLÓGICO DA REGIÃO PRODUTORA DE CRISOBERILOS PADRE PARAÍSO - AMERICANAS (ESTADO DE MINAS GERAIS - MG)"
ABSTRACT: This research was achieved by using the conventional method of prospection based on the panning of old alluvium overburdens, river beds, fluvial terraces, colluvium and pegmatites. Such a procedure was applied in order to determine the host rock of the chrysoberyl found in the Padre Paraíso - Americanas region, in the northeastern part of the Minas Gerais State. In order to define the relation between the deposits and the local basement rocks, a geological mapping of the area was also carried out. Studies on the morphological and climatic conditions associated with effect of recent cycles of erosion, as well as the main features of the detritic deposits allowed the reconstruction of the landscape and the depositional regimes, and the estimates of age of the detritical deposits with the chrysoberyl-bearing bed gravel. All the types of mineral occurrences found in the area were also described. The results show that chrysoberyl is found in old alluvium deposits of pleistocenic and holocenic ages, whose host rocks are suggested to be simple non-zoned pegmatites, which intrude granitoids of granitic to granodioritic compositions and monzogranites, weathered by recent erosion cycles. The location of the studied samples and the distribution contours (in weight %) of their main mineralogies on the geological map, allow to depict the relations between the mineral occurrences and their probable source rocks. A geomorphological map is also presented, in which main features of surfaces of erosion present in the area are briefly discussed.

NOME: AMIN MURAD
ORIENTADOR: CRISTINA MARIA WIEDEMANN
TÍTULO: "GEOLOGIA, PETROGRAFIA E GEOQUÍMICA (ELEMENTOS MAIORES E MENORES E ALGUNS TRAÇOS) DO MACIÇO INTRUSIVO DE CONCEIÇÃO DE MUQUI - ES"
ABSTRACT: The Conceição de Muqui igneous complex is located in southern Espírito Santo state and covers about 50 km2 of outcrop area. In the eastern border of the outcrop area it is emplaced in schistoid biotite porfiroblastic gneisses. In the northern and western border it is emplaced in migmatitic gneisses and at the southern border into a orthogneissic sequence associated with amphibolites and banded migmatitic gneisses. The intrusive body consists of 4 petrographic and trasitionals domains: 1) Mixed Zone A (at central-eastern border) consists of a strong interfingering of irregular rock bodies of monzonitic to dioritic composition (mainly monzodiorites), with a medium to coarse granular texture and incipient planar flow layering. 2) Mixed Zone B (at southern border), consists of more melanocratic, irregular and interfingering fine-grained rock bodies with monzonitic to dioritic compositions, with strong planar flow layering cut by felsic more leucocratic coarse-grained rocks in a network pattern. 3) Monzonitic Rocks (mainly at western border), it is one of the most homogeneous unities of the intrusive massif; it consists of a coarse-grained leucocratic rock. The flow structures were slightly developed in the central zones and strongly developed on the borders. 4) Granitic Rocks (mainly at northern border) consist of medium to coarse grained rocks which basically corresponds to an increase of quartz content in the monzonitic rocks. The intrusion is rich in sin-to-post-intrusive dikes, with dioritic to granitic compositions, intermediary composition also exists. The more felsic ones shows the younger relative ages. A post-intrusive phase consists of granitic rocks rich in enclaves, some of them containing quartz-plagioclase-titanite-allanite amygdals. Its is remarkable the composition and the interrelation evolution among feldspars. Calcic plagioclase evolves to a less sodic one. Later they became surrounded by poorly twinned alcalifeldspars, and/or micro-grained to coarse-grainde, mesoperthites. Microcline with plagioclase nucleous evolves towards a microperthitic texture with a non-perthitic border. The micro grained mesoperthites occurs mainly at the mesocratic monzonites and monzodiorites; where as the leucratic monzonites, shows coarse grained mesoperthites. The interrelation becomes simpler on the granites, where the feldspars are homogeneous. The main mafic mineral is biotite, which usually surrounds amphiboles (Fe-Hastingsite). Crystals of piroxenes (Fe-Augite and Hypersthene) occur predominantly in mafic phases, rarely evolving to amphiboles and biotites. The main accessory minerals are: titanite; allanite and zircon (more felsic phases); pyrite; magnetite; hematite; muscovite and apatite, which increases in size and amount in the mafic phases. The rocks analysed in this study belong to the High-K Monzonitic Calc-alkaline Trend (LAMEYRE & BOWDEN, 1982). The planar and/or linear flow structures are well preserved, dipping sub-horizontally in the central part of the intrusion to sub-vertically, mostly in the marginal areas. Marginal shears striking radially are common. Country rocks septa and xenolithes are abundant inside the intrusion, often discordant with foliations of the flow structures. These facts suggest, that the intrusive massif has a shallower erosion level than other studied massifs in the region. Thirty three lithogeochemical analysis showed an alkaline trend, with normative nepheline and an agpaitic index ( 1, Na/K ratio > 1, in about 50% of basic rock groups, and an inversion of this in most of the intermediary and acid rocks. High amounts of K, P, Ba, Sr and Zr are indicative of incompatible elements in the more basic rocks. Anomalous amounts of Cr and Ni in quartz-monzonites and granites suggest a mantellic source influence in the acid rocks origin. Based on field, petrographic and geochemical data assemblage, plus regional geochronological data and comparison with neighbouring massifs, the age of the intrusive body is suggested herein as Precambrian - end of the Brasiliano Cycle. The placement environment would alternate from extensional to compressional, which is very common at the end of any tectonic cycle.

NOME: MARIA LOURDES SOUZA FERNANDES
ORIENTADOR: CRISTINA MARIA WIEDEMANN
TÍTULO: "GEOLOGIA, PETROGRAFIA E GEOQUÍMICA DE ROCHAS GRANITÓIDES DA REGIÃO DE PEDRA AZUL - MG"
ABSTRACT: The granitic rocks from Pedra Azul region can be subdivided in two groups. The first one is derived from migmatitic rocks and is characterized by garnet as accessory mineral. These rocks are included in the Complexo Jequitinhonha. The second group has two porphyritic facies and one homogeneous and is intrusive in the Complexo Jequitinhonha. These rocks contain xenoliths of saccharoid granites and dark microgranular-hornblend bearing enclaves. These rocks constitute the Complexo de Medina. The granites of Complexo de Medina have signatures of I-type, are late to post-orogenic with calc-alkaline character, dominantly metaluminous, plotting in the STRECKEISEN diagram in the granitic and granodioritic fields. The elliptical form, the presence of xenocrysts and the intern foliation parallel to the bord of microgranular enclaves permit to interpret their genesis by commingling. The distribution patterns of REE of granites and enclaves are similar and compatible with a crustal origin. Allanite and titanite are responsible by REE pattern, being more concentrated in less diferenciated rocks. Field features, petrographic and geochemical data indicate that the k-feldspars megacrysts were formed together with the ones of the groundmass. All the evidences pointed to a crustal origin for granites and enclaves, being the magma mixing and magmatic diferenciation responsible by their evolution.

NOME: SORAYA ALMEIDA
ORIENTADOR: MARIA DO CARMO BUSTAMANTE JUNHO
TÍTULO: "PETROGRAFIA E GEOQUÍMICA DE ROCHAS ULTRAMÁFICAS NA REGIÃO DE LIBERDADE E CARRANCAS, MINAS GERAIS"
ABSTRACT: Six bodies of ultramafic rocks, four exposed next to Liberdade (Fazenda da Roseta, Serra da Garça, Morro do Corisco and Arantina) and two next to Carrancas (Serra do Moleque and Fazenda da Areia), are object of this study. In Liberdade, the bodies are surrounded by metasediments of Proterozoic age and, in Carrancas, they are situated at contact zones between Proterozoic metasediments and Archean basement. In both regions, the ultramafic bodies are considered allochtonous and show, at their edges, schistosity in concordance with regional structures. In those rocks, mineralogical compositions vary significantly. In Liberdade they are predominantly websterites, honblendites, spinel harzburgites and spinel orthopiroxenites in the Fazenda da Roseta body; serpentinites, spinel hornblendites and dunites in the Morro do Corisco; orthopiroxenites and rocks rich in anthophylllitic amphiboles in the Serra da Garça region and chlorites olivine fels in Arantina. In Carrancas, hornblendites, serpentinites, talc schists and talc fels are associated in the Serra do Moleque ultramafic body; spinel orthopiroxenites, serpentinites and rocks made up predominantly of chlorite are observed in the Fazenda da Areia body. Mineral parageneses in those rocks indicate metamorphism under amphibolite facies conditions. In some specimens, however, it is still possible to recognize mineralogical relations that indicate equilibration under granulite facies conditions. Eighteen samples, eleven from Liberdade and seven from Carrancas were chosen for chemical analyses. Geochemical characteristics suggest that the ultramafic bodies of Liberdade are genetically related. However, one of them, the Arantina body, showed distinct compositional behavior, similar, on the other hand, to the chemical compositions of Carrancas rocks. Genetic relations between ultramafic rocks of both regions are, however, uncertain. Mineralogical compositions and geochemical and textural data suggest that the ultramafic bodies were derived from differentiated tholeiitic magmas rather than tectonic slices of upper mantle or Alpine-type bodies.

1993

NOME: SÍLVIA REGINA DE MEDEIROS
ORIENTADOR: CRISTINA MARIA WIEDEMANN
TÍTULO: "GEOLOGIA, PETROLOGIA E GEOQUÍMICA DO MACIÇO INTRUSIVO DE VÁRZEA ALEGRE - ES"
ABSTRACT: The intrusive complex of Várzea Alegre is located at the central-northern portion of Espírito Santo State. Based on geological mapping (1:50.000), two domains were recognized: an external domain of a wide ring of charnockitic rocks and an internal domain of contrasting magnetites. The contact between the two domain is clear, although sometimes gradual (lit-par-lit, amagmatic, or nebulitic). The intrusive body, studied in detail, could be subdivided into four sub-domains, consisting of the following lithotypes: gabronorite, quartz-diorite, quartz-monzodiorite and monzonite rocks and coarse megaporphyritic granite. A small stock of fine-grained quartz-syenite crops out, in the central portion of the massif. The different lithotypes of magmatites are disposed in a nearly circular structure, with a more basic core and more acidic to intermediate margins, typical for an inversely zoned diapir. Planar flow structures tend to present almost subvertical dip angles, which are well observed nex to the contact between the internal and external domains. Petrographic and geochemical studies suggest a mantle origin for the basic and intermediate rocks and the existence of two main magmatic process of differentiation: fractional crystallization and commingling. Acid rocks seem to be related to crustal melting, induced by the rise of mantle material. Network structures, mantled porphyritic k-feldspars and embayed quartz surrounded by mafic minerals are evidence of mechanical mixing process of contrasting magmas. These features are commonly found in others plutons in the South of Espírito Santo, like Santa Angélica, Castelo and Venda Nova massifs.

1996

NOME: MARCELO ESTEVES ALMEIDA
ORIENTADOR: MARIA DO CARMO BUSTAMANTE JUNHO
TÍTULO: "GEOLOGIA, PETROGRAFIA E GEOQUÍMICA PRELIMINAR DO LEUCOGRANITO CAPIVARA, ITAMONTE, SUL DE MINAS GERAIS"
RESUMO: Os migmatitos e leucogranitos a leste de Itamonte (MG) foram gerados pelo processo metamórfico-anatético, que afetou os metassedimentos da base do Ciclo Deposicional Andrelândia I. A sequência migmatítica representa dois estágios distintos de fusão parcial, marcados por tipos metatexíticos e diatexíticos. O biotita gnaisse migmatítico (metatexito) preserva em parte as características ré-migmatização, enquanto o leucognaisse migmatítico (diatexito heterogêneo), gerado sob condições de fusão parcial mais avançada, possui estruturas pré-migmatíticas bastante destruídas. Anfibolitos e muscovita-quartzo xisto constituem resistatos do processo anatético. O leucogranito Capivara apresenta três fácies distintas, denominadas de Ribeirão da Prata, Dois Irmãos e Monte Belo. Este corpo possui contatos intrusivos, concordantes e gradativos com esta sequência migmatítica, possui composição monzogranítica e demonstra, em planta, forma lenticular, alongada na direção NE-SW. Apresenta textura equigranular à levemente porfirítica, e associação mineral essencial composta por quartzo, microclina (micropertítica), plagioclásio (albita-oligoclásio), muscovita, biotita, turmalina, granada; e acessória formada de zircão, apatita, monazita e minerais opacos. A fácies Ribeirão da Prata corresponde a um granito migmatítico ou diatexito homogêneo, e marca a transição entre o leucogranito Capivara e as rochas encaixantes migmatíticas. É caracterizada por apresentar aglomerados de biotita e porções com textura migmatítica preservada. As fácies Dois Irmãos e Monte Belo correspondem, respectivamente, a muscovita-biotita e biotita-muscovita leucogranitos, apresentando caráter intrusivo e associações minerais semelhantes, diferindo entre si, apenas, em alguns aspectos texturais e químicos. A geração do magma leucogranítico ocorreu no ápice do metamorfismo sin-Dn (principal fase de deformação), intrudindo posteriormente estruturas relativas a Dn+1. A sudeste, o leucogranito Capivara é bordejado por biotita granito porfirítico, denominado granito Maromba, que é caracterizado por apresentar-se bastante deformado, com caráter porfirítico conspícuo e matriz enriquecida em biotita. Os diagramas químicos discriminativos apontam para uma gênese envolvendo fusão crustal, em condições PT similares às observadas em ambientes de colisão continental ou de subducção do tipo-A. A origem do leucogranito Capivara e das rochas encaixantes migmatíticas, baseada na fusão parcial de material crustal, encontra embasamento nas relações de campo e petrográficas. Constata-se uma gradação contínua, que segue uma sequência baseada no aumento crescente proporcional de fusão: biotita gnaisse migmatítico (metatexito) ® leucognaisse migmatítico (diatexito heterogêneo) ® Fácies Ribeirão da Prata (granito migmatítico ou diatexito homogêneo) ® Fácies Dois Irmãos (muscovita-biotita leucogranito) ® Fácies Monte Belo (biotita-muscovita leucogranito).

NOME: CARLOS SIQUEIRA BANDEIRA DE MELLO
ORIENTADOR: HÉLIO MONTEIRO PENHA
TÍTULO: "A CONTRIBUIÇÃO DA GEOLOGIA E DA GEOQUÍMICA NA AVALIAÇÃO AMBIENTAL E NO PROGNÓSTICO DA QUALIDADE DA ÁGUA DE ABASTECIMENTO DO RIO MACAÉ, RJ"
RESUMO: Este estudo teve como objetivo enfatizar a importância das ferramentas geológicas e geoquímicas na avaliação do quadro e dos impactos ambientais decorrentes de processos naturais e /ou antropogênicas no rio Macaé, RJ, em especial no baixo curso do rio, onde concentra-se a maior parte das atividades de agricultura, pecuária bem como as estações de tratamento da água de abastecimento do município de Macaé, RJ. Para isso, realizou-se um reconhecimento geológico em 1.750 km2 correspondentes a bacia de drenagem do rio Macaé e tributários, ao longo dos 110 km de percurso desse rio. Efetuou-se, ainda um levantamento geoquímico numa área de 230 km2 , do baixo curso do rio Macaé, onde foram coletadas amostras de solos, rochas e águas. Baseados na geologia e nas análises dessas amostras, e mediante um estudo estatístico - com enfoque em backgrounds, correlações de elementos e substâncias; análise de agrupamentos e componentes principais, foi possível obter-se tanto as assinaturas geoquímicas da área estudada como também mostrar-se a importância de levantamentos desse tipo na discriminação dos impactos ambientais em sistemas naturais e/ou de origem antrópica. A análise comparativa entre os teores geoquímicos de rochas e solos indicaram a tendência dos elementos Fe, Al, Sn, Pb e V em fixarem-se nos solos. Ao que parece a incorporação desses elementos às águas do rio Macaé deve estar ocorrendo através das partículas de solos carreadas pelo runoff. Por outro lado, a mesma análise comparativa, indicou que os elementos Mn, Ba, Co, Cr, Cu, Ni, Sr, Zn, As, Si e Ca mostraram-se mais propensos à lixiviação. Por intermédio do estudo geoquímico foi possível, também, detectar-se os locais em que as condições naturais das águas estão sendo modificadas antropicamente - a exemplo do aumento do teor de nitrogênio provavelmente ligado a decomposição de alimentos e dejetos de trutas, na parte montanhosa do alto rio Macaé. De outro lado, ressaltou-se que os backgrounds litológicos naturalmente elevados das rochas, devem ser separados daqueles a origem antrópica, à exemplo do alumínio - encontrado nas águas do rio Macaé com valores coincidentes ao máximo tolerável pela legislação , devido à sua abundância em rochas oriundas de pelitos aluminosos na Unidade São Fidélis. Tais discriminações seriam difíceis de serem avaliadas, apenas com as análises químicas rotineiramente determinadas em amostras de águas de rios, sem um conhecimento prévio de geoquímica das unidades geológicas da região. No caso específico das análises de solos, os elementos Sr e Ba serviram ainda para caracterizar a Unidade Região dos Lagos devido à correlação perfeita existente entre eles. Dentre os principais impactos encontrados na região, ligados aos aspectos geológicos, reconheceu-se, avaliou-se e sugeriu-se ações mitigadoras para a melhoria da qualidade das águas do rio Macaé em: regiões sujeitas a movimentos rápidos de massa, devido a abertura de estradas e plantio de bandeiras em zonas de encostas íngremes; áreas de canais retificados do baixo rio Macaé, seus efeitos no regime de deposição dos sedimentos e as prováveis conseqüências para a biota; contaminação das águas devido ao runoff - na maioria das vezes incrementado pela descentralização geológica e vegetal nas margens do rio Macaé, bem como as bolsas que dragam areia no fundo do rio Macaé.

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